Oily Water Separator

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How Oily Water Separation Works — Gravity, Coalescence and Why Turbulence Ruins It

How oily water separation works: globule size, density and viscosity, why 60 °C and sea water help, and why turbulence destroys a coalescer's performance.

Published by ChartandKeel Updated

1. The basic mechanism

Warning: Operating rule

The maker's manual and the approved operating procedure override these notes. This chapter explains behaviour; it does not set throughput limits.

An oil globule suspended in water is acted on by two things at once: it is buoyed upwards by the difference in density between oil and water, and it is resisted by the viscosity of the water as it tries to move. Separation happens when the upward (terminal) velocity is enough to carry the globule to the surface before the water carries it out of the vessel.

That terminal velocity depends on three things, and all three are under the operator's influence to some degree:

  • the size of the oil globule — large globules rise much faster than small ones;
  • the relative density difference between oil and water — a bigger difference means a bigger driving force;
  • the viscosity of the oil — a thinner oil rises more readily than a thick one.
Chart showing the separation performance achieved against oil globule size
Figure 1: Separation performance plotted against globule size, showing how quickly the achievable effluent quality degrades once the oil is broken into fine droplets.

What encourages good separation

  • Large oil globule size. The bigger the droplet, the faster it rises. Anything that shears or churns the mixture makes the droplets smaller and the separation worse.
  • Elevated temperature. Warming the mixture increases the specific gravity differential between oil and water and reduces the viscosity of the oil. Both effects help. This is why steam heating coils are fitted and why about 60 °C is the working figure.
  • Using sea water. Sea water has a higher density than fresh water, so the density differential against the oil is greater.

What destroys separation

Turbulence and agitation. They cause mixing and re-entrainment of oil that had already separated — the oil is stirred back into the water and carried out with it. Laminar, streamlined flow is what the design is trying to achieve, and everything about the installation — the pipe sizes, the pump type, the entrance area — is arranged to get it.

2. The design features that exploit the physics

A well-designed separator is a machine for making the flow behave. The features that do it:

  • A large entrance area, so that the flow velocity is low and large slugs of oil can move to the surface quickly instead of being swept through. The low-capacity supply pump is part of this — a deliberately slow, gentle flow is the design intent, not a limitation.
  • Alternation of the flow path in a vertical direction, which repeatedly brings oil near the surface. Weirs are used to reduce the liquid depth at those points, shortening the distance the globule has to travel.
  • Angled surfaces on which oil accumulates and forms globules large enough to float away.
  • Fine gauze screens, which act as coalescing surfaces — oil wets the gauze and builds up on it until the globule is big enough to rise.

3. Two stages, always

Every practical installation separates in two stages:

  1. First stage — gravity separation. Coarse oil is floated off.
  2. Second stage — coalescence filtration. The droplets that gravity could not lift are caught and grown until they can be lifted.

The second stage works because the filter elements remove small droplets of oil and hold them until they merge into larger droplets — they coalesce — and the enlarged droplets then rise to the oil collecting space and are drained off.

Gravity, coalescing and adsorption media

Gravity separation removes free oil because buoyant droplets rise when flow is calm and residence time is adequate. A coalescer captures fine droplets on an oil-wet surface and combines them into larger drops that can separate by gravity. These are different mechanisms: the coalescer does not simply act as a sieve.

Adsorption means contaminants adhere to the surface of a medium; absorption means a fluid is taken into the body of a material. Some OWS descriptions and makers use these terms for particular polishing elements, but cartridge construction and service life vary. Identify the installed element from its maker's documentation, and do not assume every second-stage cartridge is an adsorber or that it can be cleaned and reused.

Coalescence type against absorption type

There are two different filter materials, and the distinction matters because the names sound similar but the action is opposite:

Coalescence typeAbsorption type
MaterialOleophilic — oil-attractingGlass wool
What it separatesSeparates oil out of the waterSeparates water out of the oil
RenewalFrequent replacement not requiredMust be renewed after a certain period

The way to hold it in the head: a coalescer is oleophilic, so it grabs the oil and lets the water through. An absorber is the other way round — it grabs the water. A coalescer lasts; an absorber is consumed and has to be renewed.

4. Three stages

Most installations in service are described as three-stage, and the arrangement is worth being able to sketch from memory.

The first stage is the automatic gravity separator. The second and third stages are coalescers. Effluent from the first stage enters the bottom of the second stage and passes up through the middle of the coalescer. Coalesced oil collects at the top of the coalescer, and the water discharges at the bottom and passes on to the next stage.

Sectional arrangement of the three-stage separator showing the coalescer elements
Figure 2: The internal arrangement of the same unit, showing the coalescer elements and the oil collection spaces above them.

The reason for two coalescing stages rather than one is simply that a single pass cannot reliably take the effluent from the gravity stage all the way down to 15 p.p.m. over the whole range of inlet conditions the regulation demands.